Thermal epimerization of diastereomeric Grignard reagents.
نویسندگان
چکیده
Thermal epimerization is the key to changing the endo-to-exo ratio of the diastereomeric bornyl and fenchyl Grignard reagents from 67:33 to 96:4 and from 20:80 to 80:20, respectively.
منابع مشابه
Stereoselective synthesis of marine antibiotic (-)-malyngolide and its stereoisomers.
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ورودعنوان ژورنال:
- Organic & biomolecular chemistry
دوره 7 1 شماره
صفحات -
تاریخ انتشار 2009